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Beilstein J. Org. Chem. 2011, 7, 265–269, doi:10.3762/bjoc.7.35
Graphical Abstract
Scheme 1: Reaction of furan with triplet excited carbonyls, regioselectivity.
Scheme 2: Possible pathways for the photochemical reaction of furan derivatives 1a–c.
Scheme 3: Synthesis and the photochemical reaction of furan-2-ylmethyl 2-oxoacetates 1a,b.
Figure 1: X-ray crystal structure of the macrocyclic lactone 2a.
Figure 2: 1H NMR spectra (500 MHz) for (a) the photolysate of 1a after 4 h irradiation in degassed and dried C...